Neodymium Doped Gadolinium Orthovanadate(Nd:GdVO4)

Nd:GdVO4 is an excellent laser crystal. This crystal is ideal laser host material for the DPSS (Diode pumped Solid State) micro/mini lasers as its good physical, optical and mechanical properties. It has higher slope efficiency than Nd:YAG and better thermal conductivity, higher power output than Nd:YVO4, so it is a good choice to use Nd:GdVO4 for high power output DPSS lasers.

CASTECH's Nd:GdVO4 is featured by:
    Large stimulated emission cross section at laser wavelength;
    • High absorption coefficient and wide bandwidth at pump wavelength;

    • Low dependency on pump wavelength;
    • Good thermal conductivity;
    • Low lasing threshold and high slope efficiency;
    • High laser induced damage threshold;
    • Strongly-polarized laser output.  

Specifications:

Crystal structure

 Tetragona

Space Group

 I41/amd

Lattice paramete

 a=0.721nm, b=0.635nm

Lasing Transition

 4F3/2    4I11/2

Lasing wavelength

 1062.9nm

Emission Cross Section (at 1064nm)

 7.6x10-19 cm2

Absorption Cross Section (at 808nm)

 4.9x10-19  cm2

Absorption Coefficient (at 808nm)

 74cm-1

Index of Refractivity (at 1064nm)

 n0=1.972,   ne=2.192

Thermal Conductivity (<110>)

 11.7W/(mxK)

Density

 5.47g/cm3

Nd Dopent level (atomic)

 0.1%, 0.2%, 0.3%, 0.5%, 0.7%, 1.0%...

 

Information Regarding Neodymium Laser Host Crystals

 

Crystal Nd:YVO4 Nd:GdVO4 Nd:YAG
Laser wavelengths 1064.3nm-1342.0nm 1062.9nm-1340nm 1064.2nm-1338.2nm
Emission bandwidth (linewidth at 1064nm) 0.8nm No dara 0.45nm
Effective laser cross section (emission cross section at 1064nm) 15.6x10-19cm2 7.6x10-19cm-2 6.5x10-10cm-2
Polarization Parallel to c-axis Parallel to c-axis unpolarized
Radioactive lifetime (microseconds) at 1% Nd doping -100μs -95μs 230μs
Pump wavelength 808.5nm 808.4nm 807.5nm
Peak pump absorption at 1% doping -41 cm-1 -57 cm-1  
Thermal conductivity, W/nK 5.1 11.7(Ref.7) 14
Doping concentration range 0.1-3.0% 0.1-3.0% 0.1-2.0%

Material Properties:Comparing Nd:GdVO4 and Nd:YVO4

Crystal Nd:GdVO4 Nd:YVO4
Crystal Structure,Space Group Tetragonal,141/amd tetragonal,141/amd
Lattice constants,nm a:0.721     b:0.635 a:0.721     b:0.629
Melting temperature,℃ 1780 1825
Thermal expansion@25℃, X10-6/℃
a
1.5
a
4.43
b
7.3
b
11.4
Specific heat@25℃,cal/mol K
32.6
24.6
dn/dT, x10-6/℃
4.7
2.7

 

CASTECH Warranty on Nd:GdVO4 Specifications:


• Transmitting wavefront distortion:less than λ/4 @ 633nm
• Dimension tolerance:(W±0.1mm)x(H±0.1mm)x(L+0.2mm/-0.1)
• Clear aperture:>90% central area
• Flatness: λ/8 @ 633 nm, and λ/4 @ 633nm for thickness less than 2mm
• Scratch/Dig code: 10/5 to MIL-O-13830A
• Parallelism:better than 20 arc seconds
• Perpendicularity: 5 arc minutes
• Angle tolerance:<±0.5°
• AR coating: R<0.2% at 1064nm,HR coating:R>99.8%@1064nm,T>95%@808nm

• Quality Warranty Period:one year under proper use.

 
 
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CONEX SYSTEMS TECHNOLOGY, Inc.
2880 Zanker Road, Suite 203
San Jose, CA 95134
Tel: 408-954-7329
Fax: 408-954-7330
Email: crystals@castech-us.com
 
 
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